The Geological Cycle of Atacama Desert Nitrate Deposits, Northern Chile

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Title:Main Title: The Geological Cycle of Atacama Desert Nitrate Deposits, Northern Chile
Description:Abstract: In this thesis, I investigate the origin and post-depositional evolution of nitrate deposits in the Atacama Desert, which host the largest natural nitrate accumulations on Earth. I integrate field observations with chemical and stable isotope analyses (δ¹⁸O, Δ¹⁷O, δ¹⁵N, δ³⁴S) across all deposit types. The consistently high Δ¹⁷O and δ¹⁸O values confirm an atmospheric origin linked to ozone-driven photochemical reactions. Lower isotope values in vein-hosted deposits indicate partial oxygen exchange with fossil hydrothermal waters during interaction with hot, saline, acid fluids. Geological, mineralogical, and sulfur isotope evidence further supports hydrothermal dissolution and reprecipitation of pre-existing atmospheric nitrate. Based on these results, I propose a two-stage geological cycle involving atmospheric deposition followed by tectonically driven hydrothermal recycling. Nitrogen isotope data show no significant microbial overprinting. This work demonstrates that Atacama nitrate deposits record a coupled atmospheric–geological system shaped by hyperaridity, tectonics, and magmatism.
Identifier:http://kups.ub.uni-koeln.de/id/eprint/79735 (URL)
Citation Advice:Riffo Contreras, C. J. (2026). The geological cycle of Atacama Desert nitrate deposits, Northern Chile [Doctoral dissertation, University of Cologne]. Kölner UniversitätsPublikationsServer (KUPS). http://kups.ub.uni-koeln.de/id/eprint/79735
Responsible Party
Creator:Camila Javiera Riffo Contreras (Author)
Publisher:University of Cologne (or Universität zu Köln)
Publication Year:2026
Topic
CRC1211 Topic:Climate
Related Subproject:D3
Subject:Keyword: Stable Isotope Geochemistry
Geogr. Information Topic:Environment
File Details
Filename:Dissertation_Riffo_Camila.pdf
Data Type:Text - Dissertation
File Size:7.6 MB
Date:Other: 19.01.2026 (Disputation)
Mime Type:application/pdf
Data Format:PDF
Language:English
Status:Completed
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Download Permission:Only Project Members (Download Embargo will be lifted after project end)
General Access and Use Conditions:According to the CRC1211DB data policy agreement.
Access Limitations:According to the CRC1211DB data policy agreement.
Licence:[CRC1211DB] Data policy agreement
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Publication Status:Accepted
Review Status:Not peer reviewed
Publication Type:Article
Article Type:Electronic
Source:Kölner UniversitätsPublikationsServer (KUPS)
Source Website:http://kups.ub.uni-koeln.de/id/eprint/79735
Number of Pages:115 (1 - 115)
Metadata Details
Metadata Creator:Camila Javiera Riffo Contreras
Metadata Created:28.04.2026
Metadata Last Updated:28.04.2026
Subproject:D3
Funding Phase:2
Metadata Language:English
Metadata Version:V50
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